NIAOULI ESSENTIAL OIL
SAFETY DATA SHEET (SDS)

  1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION & THE COMPANY/UNDERTAKING
1.1 Product Identifier
Product Name Niaouli Oil
Biological Definition The volatile oil obtained from the leaves of Melaleuca viridiflora, quinquenervia Myrtaceae
INCI Name Melaleuca quinquenervia Leaf Oil
Synonyms & Trade Names
CAS-No 8014-68-8 / 132940-73-9 EC No. 310-217-5 EINECS No. 310-217-5
1.2 Relative identified uses of the substance or mixture and uses advised against
No additional data available.
1.3 Details of the supplier of the safety data sheet
Essences of the Australian Bush 94 Walkers Point Road, Maryborough, Queensland, Australia.
1.4 Emergency Tel. No. 000
  1. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
The Full Text for all Hazard Statements are Displayed in Section 16.
Classification (EC 1272/2008)
Flammable liquid, Category 3 (Flam. Liq. 3, H226).

Skin irritation, Category 2 (Skin Irrit. 2, H315).

Skin sensitisation, Category 1 (Skin Sens. 1, H317).

Aspiration hazard, Category 1 (Asp. Tox. 1, H304).

2.2 Label Elements
Label in accordance with (EC) No 1272/2008
 

 

 

 

 

 

 

GHS08           GHS09          GHS07          GHS02

 

Signal Word Danger
Contains 1,8-Cineole, Alpha-terpineol, Pinenes, (R)-P-Mentha-1,8-Diene, Para-Cymene
Hazard Statements
H226                Flammable liquid and vapour.

H304                May be fatal if swallowed and enters airways.

H315                Causes skin irritation.

H317                May cause an allergic skin reaction.

H411                Toxic to aquatic life with long lasting effects.

Precautionary Statements
P273                Avoid release to the environment.

P280                Wear protective gloves/protective clothing/eye protection/face protection.

Supplementary Precautionary Statements
P301 + P310   IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302 + P352   IF ON SKIN: Wash with plenty of soap and water.

P331                Do NOT induce vomiting.

P332 + P313   If skin irritation occurs: Get medical advice/attention.

2.3 Other Hazards
PBT or vPvB according to Annex XIII The substance does not satisfy the PBT or vPvP criteria in accordance with annexe XIII of the REACH regulations EC 1907/2006.
Adverse physio-chemical properties No additional data available.
Adverse effects on human health No additional data available.
  1. COMPOSITION/INFORMATION ON INGREDIENTS
3.2 Mixtures
≤60.0% 1,8-CINEOLE CAS: 470-82-6, EC: 207-431-5

Classification (EC 1272/2008) Warning,   Flam. Liq. 3, H226,  Skin Sens. 1 – H317

≤20.0% ALPHA-TERPINEOL CAS-No.: 98-55-5 EC No.: 202-680-6

Classification (EC 1272/2008) Warning  Flam. Liq. 3, H226, Skin Irrit. 2, H315

Eye Irrit. 2, H319

≤9.4% (R)-P-MENTHA-1,8-DIENE CAS: 5989-27-5, EC: 227-813-5

Classification (EC 1272/2008) Warning, Flam. Liq. 3, H226, Skin Irrit. 2, H315, Skin Sens. 1, H317, Aquatic Acute 1, H400, M Acute = 1, Aquatic Chronic 1, H410, M Chronic = 1

≤7.0% PINENES (ALPHA OR BETA)

Classification (EC 1272/2008) Dgr Flam. Liq. 3, H226, Asp. Tox. 1, H304, Skin Sens. 1, H317, Aquatic Acute 1, H400, M Acute = 1, Aquatic Chronic 1, H410, M Chronic = 1

≤6.0% HYDROCARBONS

Classification (EC 1272/2008) Danger Asp. Tox. 1, H304

≤2.0% PARA-CYMENE CAS: 99-87-6, EC: 202-796-7

Classification (EC 1272/2008) Danger, Flam. Liq. 3, H226, Asp. Tox. 1, H304, Aquatic Chronic 2, H411,

  1. FIRST AID MEASURES
4.1 Description of first aid measures
Inhalation Remove victim immediately from source of exposure. Get medical attention if any discomfort continues.
 Ingestion Do not give the patient anything orally. In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water and consult a doctor. Seek medical attention immediately, showing the label. If swallowed accidentally, do not allow to drink, do not induce vomiting and transfer to hospital immediately by ambulance. Show the label to the doctor.
Skin Contact Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner. Watch out for any remaining product between skin and clothing, watches, shoes, etc. In the event of an allergic reaction, seek medical attention.

If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred to hospital.

Eye Contact Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention immediately. Continue to rinse.
4.2 Most important symptoms and effects, both acute and delayed
No additional data available.
4.3 Indication of any immediate medical attention and special treatment needed
No additional data available.
  1. FIRE-FIGHTING MEASURES
5.1 Extinguishing Media
Chemical powders, carbon dioxide and other extinguishing gas are suitable for small fires.

Keep packages near the fire cool, to prevent pressurised containers from bursting.

5.2 Special hazards arising from the product
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.

Do not breathe in smoke.

In the event of a fire, the following may be formed :

- carbon monoxide (CO)

- carbon dioxide (CO2)

5.3 Advice for firefighters
Fire-fighting personnel are to be equipped with autonomous insulating breathing apparatus.
  1. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Consult the safety measures listed under headings 7 and 8.

For non first aid worker

Avoid any contact with the skin and eyes.

For first aid worker

First aid workers will be equipped with suitable personal protective equipment (See section 8).

6.2 Environmental Precautions
Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums for waste disposal.

Prevent any material from entering drains or waterways.

If the product contaminates waterways, rivers or drains, alert the relevant authorities in accordance with statutory procedures

Use drums to dispose of collected waste in compliance with current regulations (see section 13).

6.3 Methods and material for containment and cleaning up.
Clean preferably with a detergent, do not use solvents.
6.4 Reference to other sections
No additional data available.
  1. HANDLING AND STORAGE
7.1 Precautions for safe handling
Individuals with a history of skin sensitisation should not, under any circumstance, handle this substance.

Always wash hands after handling.

Remove and wash contaminated clothing before re-using.

Remove contaminated clothing and protective equipment before entering eating areas.

Fire prevention :

Handle in well-ventilated areas.

Prevent the formation of flammable or explosive concentrations in air and avoid vapour concentrations higher than the occupational exposure limits.

Never inhale this substance.

Prevent the accumulation of electrostatic charges with connections to earth.

Use the mixture in premises free of naked flames or other sources of ignition and ensure that electrical equipment is suitably protected.

Keep packages tightly closed and away from sources of heat, sparks and naked flames.

Do not use tools which may produce sparks. Do not smoke.

Prevent access by unauthorised personnel.

Recommended equipment and procedures :

For personal protection, see section 8.

Observe precautions stated on label and also industrial safety regulations.

Prohibited equipment and procedures :

No smoking, eating or drinking in areas where the substance is used.

Never open the packages under pressure.

7.2 Conditions for safe storage, including any incompatibilities
Storage

Keep the container tightly closed in a dry, well-ventilated place.

Keep away from food and drink, including those for animals.

Keep away from all sources of ignition - do not smoke.

Keep well away from all sources of ignition, heat and direct sunlight.

Avoid accumulation of electrostatic charges.

Packaging

Always keep in packaging made of an identical material to the original.

7.3 Specific end use(s)
No additional data available.
  1. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters
No additional data available.
8.2 Exposure controls
Protective Equipment
Process Conditions Provide eyewash station.
Engineering Measures Provide adequate ventilation.
Respiratory Equipment For high concentrations use respiratory equipment.
Hand Protection Use suitable protective gloves that are resistant to chemical agents in accordance with standard EN374.

Gloves must be selected according to the application and duration of use at the workstation.

Protective gloves need to be selected according to their suitability for the workstation in question : other chemical products that may be handled, necessary physical protections (cutting, pricking, heat protection), level of dexterity required.

Recommended properties :

- Impervious gloves in accordance with standard EN374

Eye Protection Avoid contact with eyes.

Use eye protectors designed to protect against liquid splashes.

Before handling, wear safety goggles in accordance with standard EN166.

Other Protection Use personal protective equipment that is clean and has been properly maintained.

Store personal protective equipment in a clean place, away from the work area.

Hygiene Measures Good personal hygiene practices are always advisable, especially when working with chemicals / oils. Never eat, drink or smoke during use. Remove and wash contaminated clothing before re-using. Ensure that there is adequate ventilation,

especially in confined areas.

Personal Protection Use personal protection according to Directive 89/686/EEC.
Skin Protection Avoid skin contact.

Wear suitable protective clothing.

Suitable type of protective clothing :

In the event of substantial spatter, wear liquid-tight protective clothing against chemical risks (type 3) in accordance with EN14605 to prevent skin contact.

In the event of a risk of splashing, wear protective clothing against chemical risks (type 6) in accordance with EN13034 to prevent skin contact.

Work clothing worn by personnel shall be laundered regularly.

After contact with the product, all parts of the body that have been soiled must be washed.

Environmental Exposure Controls Avoid discharging into drainage water. Only eliminate by authorised companies.
  1. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearance Liquid.
Colour Colourless to pale yellow.
Odour Characteristic.
Relative Density 0.903 - 0.924 @ 20°C
Flash Point (°C) 23°C <= PE <= 55°C
Refractive Index 1.465 – [email protected] 20°C
Melting Point (°C) No additional data available.
Boiling Point (°C) No additional data available.
Vapour Pressure No additional data available.
Solubility in Water @20°C Insoluble in water.
Auto-ignition temperature (°C) No additional data available.
9.2 Other information
No additional data available.
  1. STABILITY AND REACTIVITY
10.1 Reactivity
No dangerous reactions known.
10.2 Chemical stability
This substance is stable under the recommended handling and storage conditions in section 7.
10.3 Possible hazardous reactions
No additional data available.
10.4 Conditions to Avoid
Any apparatus likely to produce a flame or to have a metallic surface at high temperature (burners, electric arcs, furnaces etc.) must not be allowed on the premises.

Avoid :

- accumulation of electrostatic charges.

- heating

- heat

- flames and hot surfaces

10.5 Incompatible materials
No additional data available.
10.6 Hazardous Decomposition Products
The thermal decomposition may release/form :

- carbon monoxide (CO)

- carbon dioxide (CO2)

  1. TOXOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute Toxicity May cause irreversible damage to the skin; namely inflammation of the skin or the formation of erythema and eschar or oedema following exposure up to four hours.

May cause an allergic reaction by skin contact.

Aspiration toxicity includes severe acute effects such as chemical pneumonia, varying degrees of pulmonary injury or death following

aspiration.

Skin corrosion / irritation No additional data available.
Serious eye damage / irritation No additional data available.
Respiratory or skin sensitisation No additional data available.
Germ Cell Mutagenicity No additional data available.
Carcinogenicity No additional data available.
Reproductive toxicity No additional data available.
STOT-single exposure No additional data available.
STOT-repeated exposure No additional data available.
Aspiration hazard May be fatal if swallowed and enters airways.

Aspiration toxicity includes severe acute effects such as chemical pneumonia, varying degrees of pulmonary injury or death following

aspiration.

Photo-toxicity No additional data available.
Other Information No additional data available.
  1. ECOLOGICAL INFORMATION
12.1 Toxicity
Toxic to aquatic life with long lasting effects.

The product must not be allowed to run into drains or waterways.

12.2 Persistence & degradability
Degradability : No data available.
12.3 Bioaccumulation Potential
Bioaccumulative potential : No data available on bioaccumulation.
12.4 Mobility in soil
No additional data available.
12.5 Results of PBT and vPvB Assessment
No additional data available.
12.6 Other adverse effects
No additional data available.
  1. DISPOSAL CONSIDERATIONS
13.1 Waste treatment  methods
Do not pour into drains or waterways.

Waste :

Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water, air, soil, plants or animals.

Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company.

Do not contaminate the ground or water with waste, do not dispose of waste into the environment.

Soiled packaging :

Empty container completely. Keep label(s) on container.

Give to a certified disposal contractor.

  1. TRANSPORT INFORMATION
14.1 UN number
UN No. Road 1169
UN No. SEA 1169
UN No. AIR 1169
14.2 UN proper shipping name
UN1169=EXTRACTS, AROMATIC, LIQUID
14.3 Transport hazard class(es)
ADR/RID/ADN Class 3

ADR/RID/ADN Class Class 3

IMDG Class 3

ICAO Class/Division 3

Transport Labels

14.4 Packing group
ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5 Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant

 

14.6 Special precautions for user
EMS F-E,S-D

Emergency Action Code F1

Hazard No. (ADR) 90 Environmentally hazardous substance

Tunnel Restriction Code (D/E)

14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC code
No additional data available
  1. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 Chemical safety assessment
No additional information available.
  1. OTHER INFORMATION
Hazard and/or Precautionary Statements in Full H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

H411 Toxic to aquatic life with long lasting effects.

Other Information None
Revision Date 01/12/2016
Reason for revision Updated
Rev No/Repl, SDS Generated 03 replaces 02

Disclaimer: The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Essences from the Australian Bush be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Essences from the Australian Bush has been advised of the possibility of such damages.